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3 Dynamics of NBTI degradation and recovery

When subjecting a PMOS device to NBTS, the amount of degradation is reported to increase gradually as a function of stress time, electric field and temperature, leading to a characteristic reduction of the MOSFET performance. However, once the stress bias is removed, at least a certain fraction of the total (math image) shift is reported to recover very quickly, making the delay between the point of time of stress termination and the first measured point recorded at the threshold voltage of the device (\( t_\mathrm {R} \)) an important parameter, which crucially determines the amount of degradation detected at the end of stress (\( t_\mathrm {S} \)). The degradation and the recovery of the threshold voltage shift may be approximated empirically by power-laws:

(3.1) \{begin}{align} \label {e:power-law} \Delta V_\mathrm {TH} (t_\mathrm {S}, t_\mathrm {R}) = A_\mathrm {S} (E_\mathrm {OX,S},T_\mathrm {S})
t_\mathrm {S}^{n_\mathrm {S}} - A_\mathrm {R} (V_\mathrm {GR},T_\mathrm {R}) t_\mathrm {R}^{n_\mathrm {R}} = A_\mathrm {S} t_\mathrm {S}^{n_\mathrm {S}} \left (1-\frac {A_\mathrm {R}}{A_\mathrm {S}}\frac
{t_\mathrm {R}^{n_\mathrm {R}}}{t_\mathrm {S}^{n_\mathrm {S}}}\right ), \{end}{align}

where the pre-factors \( A_\mathrm {S} (E_\mathrm {OX,S},T_\mathrm {S}) \) and \( A_\mathrm {R} (E_\mathrm {OX,R},T_\mathrm {R}) \) are reported to depend on the oxide field during stress ((math image)) and recovery ((math image)) as well as on the stress temperature ((math image)) and the recovery temperature ((math image)). The power-law exponents \( n_\mathrm {S} \) and \( n_\mathrm {R} \) determine the degradation and recovery dynamics as a function of the stress ((math image)) and the recovery time ((math image)). \( n_\mathrm {S} \) and \( n_\mathrm {R} \) are extracted from the slope of the (math image) shift in a double-logarithmic plot \( \Delta V_\mathrm {TH}^\mathrm {S} \) vs. (math image), and \( \Delta V_\mathrm {TH}^\mathrm {R} \) vs. (math image) respectively. Note that the second term in Eq. 3.1 accounts for power-law-like recovery after interrupting the stress phase. It may be neglected when the stress time ((math image)) exceeds the measurement delay ((math image)) by far (provided the overall dynamics of degradation and recovery are similar).

Long-term degradation ((math image) \( \geq 1-10\,\mathrm {s} \)) is reported to follow a typical power-law-like increase with \( 0.1 < n_\mathrm {S} < 0.4 \). On the other hand, short-term degradation ((math image) \( < 1\,\mathrm {s} \)) and recovery show much smaller power-law exponents (\( n_\mathrm {S} \) and \( n_\mathrm {R} \leq 0.1 \)), allowing to approximate Eq. 3.1 by logarithmic time dependences. This can be easily demonstrated by expanding the power-law relations in Eq. 3.1 in Taylor series around small values of \( t_\mathrm {S0} > 0 \), and \( t_\mathrm {R0} > 0 \), respectively, yielding

(3.2–3.3) \{begin}{align} \label {e:power-law-2} \Delta V_\mathrm {TH} (t_\mathrm {S}, t_\mathrm {R}) &\approx A_\mathrm {S} t_\mathrm
{S0}^{n_\mathrm {S}} - A_\mathrm {R} t_\mathrm {R0}^{n_\mathrm {R}} + n_\mathrm {S} A_\mathrm {S} \log \left (\frac {t_\mathrm {S}}{t_\mathrm {S0}}\right ) - n_\mathrm {R} A_\mathrm {R} \log \left (\frac
{t_\mathrm {R}}{t_\mathrm {R0}}\right ), \\ &\approx \log \left (\frac {t_\mathrm {R0}^{B_\mathrm {R}} t_\mathrm {S}^{B_\mathrm {S}}} {t_\mathrm {S0}^{B_\mathrm {S}} t_\mathrm {R}^{B_\mathrm
{R}}}\right ), \{end}{align}

where \( B_\mathrm {S} = n_\mathrm {S} A_\mathrm {S} \) is the degradation rate and \( B_\mathrm {R} = n_\mathrm {R} A_\mathrm {R} \) is the recovery rate in mV/decade. Assuming NBTI to be caused by hole trapping within the gate oxide (as it is possibly the case for short stress times), \( t_\mathrm {S0} \) and \( t_\mathrm {R0} \) can be approximated by the minimum capture time constant \( \tau _\mathrm {c0} \) and the minimum emission time constant \( \tau _\mathrm {e0} \) at the particular stress/relax conditions after Huard et al. [51]. Universality of recovery traces (\( \Delta V_\mathrm {TH} \) vs. \( t_\mathrm {S}/t_\mathrm {R} \)) recorded at different stress times has been demonstrated by Grasser et al. in [52] and may be obtained when assuming \( B_\mathrm {S} = B_\mathrm {R} \) and \( t_\mathrm {S0} = t_\mathrm {R0} \gg t_\mathrm {S} \) and \( t_\mathrm {R} \), yielding the following simplified expression for the threshold voltage shift:

(3.4) \{begin}{align} \label {e:power-law-3} \Delta V_\mathrm {TH} (t_\mathrm {S}, t_\mathrm {R}) &\approx B_\mathrm {R} (E_\mathrm {OX,S},T_\mathrm
{S},E_\mathrm {OX,R},T_\mathrm {R}) \log \left (1 + \frac {t_\mathrm {S}}{t_\mathrm {R}}\right ). \{end}{align}

When neglecting recovery (\( t_\mathrm {R} \approx 0 \)), we may derive the degradation dynamics from Eq. 3.2 as follows:

(3.5) \{begin}{align} \label {e:power-law-4} \Delta V_\mathrm {TH} (t_\mathrm {S}, 0) = \Delta V_\mathrm {TH}^\mathrm {OTF} (t_\mathrm {S}) &\approx
B_\mathrm {S} (E_\mathrm {OX,S},T_\mathrm {S}) \log \left (\frac {t_\mathrm {S}}{t_\mathrm {S0}}\right ). \{end}{align}

In [53] universal scalability of the short-term and long-term degradation and the recovery has been demonstrated for different stress fields, temperatures and oxide thicknesses suggesting either a single mechanism or at least tightly coupled phenomena to be responsible for NBTI induced degradation and recovery.

The dynamics of both branches, namely the evolution of the degradation as a function of the stress time, field and temperature and the evolution of the recovery as a function of the recovery time, field and temperature, are very important indicators used to evaluate the NBTI stability of a technology and to check theoretical predictions derived from particular physical models. Since degradation usually follows a power-law with \( n_\mathrm {S} > 0.1 \) (except for short stress times) which cannot be perceived as log-like, it is typically described by the pre-factor \( A_\mathrm {S} \) and/or the power-law exponent \( n_\mathrm {S} \). On the other hand, (at least when being far away from recovery saturation) relaxation usually follows a power-law with \( n_\mathrm {R} \leq 0.1 \) which is similar to log-like. Hence, the recovery rate per decade (pre-factor \( B_\mathrm {R} \)) in mV/dec (when measuring (math image)) recovery or in A/dec (when measuring CP current recovery) can be used to fully describe relaxation dynamics.

In this chapter, different techniques are presented which allow to investigate the dynamics of defect generation and recovery under AC and DC bias conditions as a function of stress time, recovery time, temperature and electric field. By means of case studies performed optionally on thin high–\( \kappa   \) and/or thick SiO\( _\mathrm {2} \) devices, fundamental experimental signatures of NBTI are revealed helping to catch a glimpse of the multi-faceted features and complexity of the problem.

3.1 Static MSM and OTF

So far, the two most frequently used measurement techniques for evaluating NBTI dynamics during stress and recovery are the classical measure/stress/measure (MSM) technique and the OTF measurement method [54]. Both techniques have certain advantages and drawbacks making the method of choice dependent on the particular problem [55, 56]. The biasing conditions applied during static MSM and OTF are schematically depicted in Fig. 3.1.

Figure 3.1:  A schematic illustration of the gate and drain bias conditions applied during MSM (a) and OTF (b). When performing MSM (a), the drain current degradation and recovery is monitored after subsequent stress runs typically at the threshold voltage of the device (open squares) thereby interrupting the stress phase repeatedly by switching the gate bias from the stress level (\( V_\mathrm {GS,stress} \)) to the \( V_\mathrm {TH} \). The stress-recovery intervals usually follow a geometric progression where the stress time equals the recovery time. For calculating the \( V_\mathrm {TH} \) shift the virgin drain current (full square) is taken as a reference. When performing OTF (b), the drain current degradation is measured directly under stress bias conditions making the measurement recovery-free (\( t_\mathrm {R} \) = \( 0\,\mathrm {s} \)). The first current value recorded under stress conditions (\( I_\mathrm {D0}^\mathrm {OTF} \); full square) is taken as a reference for calculating the \( V_\mathrm {TH} \) shift.

When applying the MSM technique, a single device is usually stressed repeatedly with increasing stress ((math image)) and recovery times ((math image)) following a geometric progression. Thereby it is usually assumed that the amount of defect relaxation occurring during the last recovery period is fully restored at the end of the subsequent longer-lasting stress run. After each stress run, the gate bias is switched from the stress level (\( V_\mathrm {GS,stress} \)) to the threshold voltage of the device. In parallel the drain bias is switched from 0.0\( \,\mathrm {V} \) to the particular read-out bias ((math image)) initializing the drain current measurement (math image) as a function of the recovery time (math image), and the stress time (math image), respectively. In the data analysis, the drain current degradation (recorded at the threshold voltage) is converted into a corresponding (math image) shift ((math image)) by assigning the degraded current values a corresponding gate voltage recorded at the virgin device, cf. Chapter 2.

Hence, the MSM technique provides the feature to analyze (math image) shifts as a function of the stress and the recovery time, the gate bias being typically (but not necessarily) close to the threshold voltage of the device during read-out. One important drawback of the technique is the fact that the extracted (math image) shifts are always afflicted with an unknown amount of recovery occurring between the point of time after removal of the stress bias and the first measurement of the drain current at the threshold voltage of the device, cf. Eq. 3.1. For experimental reasons, the switching event and the following measurement cannot be performed arbitrarily fast (\( \geq 1\,\mathrm {\mu s} \)), leaving much room for speculation what happens within the first couple of nanoseconds after terminating stress. Until now, only a few groups claim that they seriously succeed in finding a plateau in their (math image) recovery curves at very early recovery times. By using the Ultra-Fast VT (UFV) measurement method [57], a minimum delay time in the range of microseconds was achieved [58, 59]. Although quite promising, a possible explanation for this observed plateau has been given in [60] as being due to the difficulty of synchronizing the recovery time scale with the real end of stress. In most reported cases, however, the extracted recovery curves are straight lines in a logarithmic time plot, indicating a very low starting time of the recovery event which remains apparently inaccessible even when advancing toward the microsecond regime [61].

When applying the OTF technique, the drain current degradation is monitored directly under stress bias conditions, making the measurement procedure itself quasi recovery-free. At the moment the gate bias is switched from the threshold voltage to the stress level (\( V_\mathrm {GS,stress} \)), the drain current measurement is started instantaneously, with the read-out drain bias applied also during stress. In order to convert the degraded drain currents recorded under stress bias conditions ((math image)) into corresponding (math image) shifts ((math image)), the first current value recorded at \( V_\mathrm {GS,stress} \) is usually considered as virgin (\( I_\mathrm {D0}^\mathrm {OTF} \)), yielding the following expression for the threshold voltage shift measured during OTF (cf. Eq. 2.5):

(3.6) \{begin}{align} \label {e:dvth-otf} \Delta {V_\mathrm {TH}^\mathrm {OTF}}(t_\mathrm {S}) \approx (V_\mathrm {GS} - V_\mathrm {TH}) \frac {I_\mathrm
{D}^\mathrm {OTF}(t_\mathrm {S}) - I_\mathrm {D0}^\mathrm {OTF}}{I_\mathrm {D0}^\mathrm {OTF}} = (V_\mathrm {GS} - V_\mathrm {TH}) \frac {\Delta I_\mathrm {D}^\mathrm {OTF}(t_\mathrm {S})}{I_\mathrm
{D0}^\mathrm {OTF}}. \{end}{align}

As opposed to the (math image) shift measured at the actual threshold voltage of the device, (math image) contains a parasitic component caused by mobility degradation (cf. 2.1.2) making it difficult to compare (math image) and (math image) directly. In order to estimate the parasitic mobility impact of (math image), the classical OTF technique has been extended to a so-called second level or three level OTF procedure were the gate voltage is varied slightly around the stress bias \( V_\mathrm {GS,stress} \) every time a drain current measurement is required allowing to estimate the variation of the transconductance around the stress voltage [54]. Besides the mobility influence, the OTF technique suffers from an additional handicap concerning the definition of the first measured drain current value \( I_\mathrm {D,lin0} \): Eq. 3.6 assumes \( I_\mathrm {D,lin0} \) to be the virgin drain current at the stress voltage, however, when considering degradation and recovery as similarly fast, \( I_\mathrm {D,lin0} \) is actually already degraded to a certain degree, again leaving much room for speculation about what happens in the first picoseconds after initiating stress [62]. From an application point of view, the OTF technique is only feasible when studying thin oxide technologies having their stress biases (\( V_\mathrm {GS,stress} \)) not far away from their threshold voltages ((math image)). This is because the signal vs. noise resolution of the relative drain current degradation decreases linearly when increasing the gate voltage overdrive, cf. Eq. 2.5.

Figure 3.2:  Degradation (open diamonds) and recovery (full diamonds) of the threshold voltage shift recorded for 100\( \,\mathrm {s} \) at 125 °C on a 1.5\( \,\mathrm {nm} \) high–\( \kappa   \) PMOS device (HK2P/1.5/1). In (a), the \( V_\mathrm {TH} \) shifts are illustrated in a lin-lin plot, in (b), the same data is illustrated in a log-log plot. The threshold voltage shift during stress (\( V_\mathrm {GS,stress} \) = -\( 2.0\,\mathrm {V} \)) was calculated using Eq. 3.6. \( I_\mathrm {D,lin0} \) was measured 10\( \,\mathrm {ms} \) after applying stress. The threshold voltage shift during recovery (\( V_\mathrm {GS,rec} \) = -\( 0.3\,\mathrm {V} \)) was calculated by referencing the degraded drain current measured at \( V_\mathrm {TH} \) to the virgin transfer curve. Between the last measured point under stress conditions and the first measured point under recovery conditions there is a 24\( \,\mathrm {mV} \) gap which may be attributed to a mobility component in \( \Delta   \)\( V_\mathrm {TH}^\mathrm {OTF} \) and to fast recovery within the first 10\( \,\mathrm {ms} \) after removal of stress.

In order to demonstrate the dynamics of NBTI stress and recovery, a 1.5\( \,\mathrm {nm} \) high–\( \kappa   \) PMOS device equipped with a p\( ^\mathrm {++} \) gate poly (HK2P/1.5/1) was stressed for 100\( \,\mathrm {s} \) at 125 °C using a stress voltage of -2.0\( \,\mathrm {V} \), cf. Fig. 3.2. Following Eq. 1.7, -2.0\( \,\mathrm {V} \) corresponds to an oxide field of approximately 6.6\( \,\mathrm {MV/cm} \). During the stress period, the linear drain current ((math image) = -\( 0.1\,\mathrm {V} \)) was monitored and (math image) was calculated using Eq. 3.6. \( I_\mathrm {D,lin0} \) was measured 10\( \,\mathrm {ms} \) after applying the stress bias. Subsequently to the stress phase, the gate bias was switched to the threshold voltage of the device (-0.3\( \,\mathrm {V} \)) recording the linear drain current then under recovery bias conditions. During recovery, (math image) was calculated by referencing the degraded drain current to a gate voltage corresponding to the virgin transfer curve. As can be seen in Fig. 3.2 (a), during stress the threshold voltage shift ((math image)) increases rapidly achieving 44\( \,\mathrm {mV} \) after 100\( \,\mathrm {s} \) stress. At that moment, the stress bias is switched from -2.0\( \,\mathrm {V} \) to -0.3\( \,\mathrm {V} \), the obtained threshold voltage shift measured under recovery conditions ((math image)) is considerably reduced by 24\( \,\mathrm {mV} \) within the first 10\( \,\mathrm {ms} \) after removal of the stress bias. The large (math image) gap between the last measured point of (math image) and the first measured point of (math image) indicates fast recovery, although probably not the entire 24\( \,\mathrm {mV} \) gap may be attributed to trap annealing since (math image) is likely to contain an offset caused by mobility degradation.

Fig. 3.2 (b) illustrates that both (math image) and (math image) increase and decrease more or less linearly in a double logarithmic diagram indicating a power-law-like correlation between degradation and stress time ((math image)) as well as between relaxation and recovery time ((math image)) as suggested in Eq. 3.1. Note that due to the small power-law factor associated with recovery, we may describe the relaxation branch also as being log-like with a recovery rate of \( B_\mathrm {R} \) = -\( 3.0\,\mathrm {mV/dec} \). The power-law factor measured during OTF stress ((math image)) is found to be 0.18 which is pretty close to the factor 1/6 often reported in literature. The kink in the stress curve visible at early stress times may be a consequence of the fact that \( I_\mathrm {D,lin0} \), measured 10\( \,\mathrm {ms} \) after applying the stress bias, is actually already degraded to a certain degree, distorting the (math image) shift evaluation in particular at the beginning of the stress phase where the overall (math image) degradation is low.

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