According to [16, 51] the appearance of vacancies in a lattice can be explained by thermodynamical arguments. Suppose atoms are taken away from lattice positions and migrated to the surface leaving back vacancies. This kind of
defects are called Schottky defects illustrated in Figure B.1. By assuming an atom positioned on a lattice site has the energy and an empty position has zero energy the
state energy of a lattice with defects can be expressed by

As the vacancies are indistinguishable the number of distinct ways of distributing vacancies in a lattice with lattice sites is given by

For a micro-canonical assembly, the entropy is defined by

Employing Stirlingβs approximation for big

and omitting the terms of the order of results in

With (B.1) the entropy can be expressed as a function of the state energy and can further be related to the temperature by

resulting in

The final result can be rewritten giving

which makes only sense when the ratio is much less then one. Otherwise the solid would by perforated with holes and collapse. For a typical energy value of
is in the range of 39 and the ratio of vacancies to the total available sites is in the order of at room temperature. For small temperature the vacancy to lattice sites ratio
function converges to

and has the form of an Arrhenius law used in the modeling of electromigration introduced in Chapter 3.
The specific heat for vacancy formation can be calculated by [48]

and vanishes at low temperature due to the excitation gaps. At high temperature the energy spectrum is bounded from above. For practically used materials not only the configuration entropy but also other entropies like the
vibration entropy are present.
Still the derivation shows that in a real crystal lattice vacancies are always present.