List of Symbols

Physical Quantities

Symbol

Description

Unit

a

width of a crystal unit cell

μm

αCO

production ratio of CO

1

b

height of a crystal unit cell

μm

B

parabolic rate coefficient

m2/s

B/A

linear rate coefficient

m/s

C

initial enhancement parameter

μm/s

C*, C0

concentration of the oxidants in the gas
ambient and at the oxide surface

cm-3

Cact

active dopant concentration

cm-3

CC, CCI, CCS

concentrations of C, C interstitial, and C at the oxide surface

cm-3

CC0

solubility limit of C

cm-3

Cinit

initial active dopant concentration

cm-3

CO, COS

concentrations of O and O at the oxide
surface

cm-3

Cth

threshold concentration

cm-3

Ctot

total doping concentration

cm-3

CS

concentration of the oxidants at the
interface

cm-3

CSi, CSiI, CSiS

concentrations of Si, Si interstitials, and Si at the oxide surface

cm-3

CSi0

solubility limit of Si

cm-3

Css

solid solubility

cm-3

D

oxidant diffusion coefficient in the oxide

m2/s

DC, DO, DSi

diffusion coefficient of C, O, and Si

m2/s

E

energy

eV

Ea

activation energy

eV

EA, ED

ionization energy of acceptors and donors

eV

EB

breakdown field

MV/cm

EC

bottom edge of the conduction band

eV

EF

Fermi level

eV

EV

top edge of the valence band

eV

Eg

energy bandgap

eV

εs

relative dielectric constant

1

η, η’

oxidation rate of Si and C interstitials on the oxide surface

1

F1-3

oxidation fluxes

cm-2 s-1

Fact

empirical scalar parameter

1

gA, gD

spin degeneracy factor of acceptors and donors

1

h

gas-phase transport coefficient

m/s

H

inverse Henry’s law constant

mol/m3Pa

k

reaction rate coefficient

cm3 mol-1 s-1

k0

initial interfacial oxidation rate

m/s

ks

surface oxidation rate coefficient

m/s

kSi, km, ka, kC

oxidation growth rates in direction of the Si-, m-, a-, and C-face

s-1

κ

characteristic reaction rate

s-1

κ1/2, κ1/2

oxidation rates of Si and C interstitials on the oxide surface

m/s

L

characteristic length

μm

λ

thermal conductivity

W/cm K

MC

number of equivalent minima in the
conduction band

1

me*, mh*

effective mass of electrons and holes

kg

μn

electron mobility

cm2/Vs

μp

hole mobility

cm2/Vs

n

electron concentration

cm-3

ni

intrinsic carrier concentration

cm-3

N

number of oxidant species

cm-3

NA, ND

acceptor and donor concentration

cm-3

NC, NV

effective density of states in the conduction and valence band

cm-3

νSi, νC

emission ratio of Si and C

1

p

hole concentration

cm-3

px

partial pressure

Pa

R1/2

half-maximal electrical activation ratio

1

Ract

electrical activation ratio

1

Ractn, Ractp

electrical activation ratio of n-type and
p-type doping

1

Rmax, Rmin

maximal and minimal electrical activation ratio

1

ρ

density of a crystal unit cell

g/cm-3

ρC, ρV

density of states in the conduction and
valence band

cm-3

t

time

s

T

temperature

°C

tA

annealing time

min

TA

annealing temperature

°C

Tip

temperature at the inflection point

°C

Tmelt

melting point

°C

x, y, z

direction vector coordinates

1

\(\hat{X}\)

normalized oxide thickness

1

X

thickness of the oxide

μm

Xinit

initial thickness of the oxide

μm

Xmax

maximal thickness of the oxide

μm

Z

pre-exponential factor

cm-3

Physical Constants

Symbol

Description

Value

h

Planck constant

6.62607 · 10-34 Js

kB

Boltzmann constant

1.38065 · 10-23 JK-1

m0

rest mass of an electron

9.10938 · 10-31 kg

R

ideal gas constant

8.31446 J K-1 mol-1